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Question

Vapour phase refining of nickel is carried out using:

A
I2
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B
Cl2
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C
HCl
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D
CO
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Solution

The correct option is B CO
Ni+4CO330350K−−−−−Ni(CO)4
Ni(CO)4450470K−−−−−Ni+4CO

Nickel is heated in a stream of carbon monoxide to form a volatile complex named as nickel tetracarbonyl. This complex is decomposed at a higher temperature to obtain pure metal.

Option D is correct.

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