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Question

Vapour pressure of a liquid A is more that of B. Which of these liquids has higher critical temperature in their gaseous state? Justify.

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Solution

Critical temperature is defined as the temperature at which a gas can be liquified,
So, the gas having higher vapour pressure liquifies at lower temperature and will have lower critical temperature and gas with lower vapour pressure will have higher critical temperature.
Hence, B has higher critical temperature.

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