Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot p_total’ p_chloroform’ and p_acetone as a function of x_acetone. The experimental data observed for different compositions of mixture is.

100 ×x_acetone

0

11.8

23.4

36.0

50.8

58.2

64.5

72.1

p_acetone/mm Hg

0

54.9

110.1

202.4

322.7

405.9

454.1

521.1

p_chloroform/mm Hg

632.8

548.1

469.4

359.7

257.7

193.6

161.2

120.7

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Solution

From the question, we have the following data

100 ×x_acetone

0

11.8

23.4

36.0

50.8

58.2

64.5

72.1

p_acetone/mm Hg

0

54.9

110.1

202.4

322.7

405.9

454.1

521.1

p_chloroform/mm Hg

632.8

548.1

469.4

359.7

257.7

193.6

161.2

120.7

p_tota(mm Hg)

632.8

603.0

579.5

562.1

580.4

599.5

615.3

641.8

It can be observed from the graph that the plot for the p_total of the solution curves downwards. Therefore, the solution shows negative deviation from the ideal behaviour.

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Similar questions

Q. Vapour pressures of pure acetone and chloroform at

328 K

are

741.8 m m H g

and

632.8 m m H g

respectively. Assuming that they form ideal solution over the entire range of composition, plot

p_{t o t a l}, p_{c h l o r o f o r m}

, and

p_{a c e t o n e}

as a function of

x_{a c e t o n e}

. The experimental data observed for different compositions of mixture is:

$100 x x_{a c e t o n e}$	$0$	$11.8$	$23.4$	$36.0$	$50.8$	$58.2$	$64.5$	$72.1$
$P_{a c e t o n e} / m m H g$	$0$	$54.9$	$110.1$	$202.4$	$322.7$	$405.9$	$454.1$	$521.1$
$P_{c h l o r o f o r m} / m m H g$	$632.8$	$548.1$	$469.4$	$359.7$	$257.7$	$193.6$	$161.2$	$120.7$

Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative deviation from the ideal solution.

QUESTION 2.37

Vapour pressures of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot $p_{t o t a l}$ , $p_{c h l o r o f o r m}$ and $p_{a c e t o n e}$ . The experimental data observed for different compoisition of mixture is:

$\begin{matrix} 100 x_{a c e t o n e} & 0 & 11.8 & 23.4 & 36.0 & 50.8 & 58.2 & 64.5 & 72.1 p_{a c e t o n e} / m m H g & 0 & 54.9 & 110.1 & 202.4 & 322.7 & 405.9 & 454.1 & 521.1 p_{c h l o r o f o r m} / m m H g & 632.8 & 548.1 & 469.4 & 359.7 & 257.7 & 193.6 & 161.2 & 120.7 \end{matrix}$

Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative deviation from the ideal solution.

Place the cards in the right boxes in the given boxes.
(a)

(b)

Observe the following figures and write the same in base 2 system by grouping.

Example:

Q. Translate the below figure to

1 ↓ 1 \to .

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100 ×x_acetone	0	11.8	23.4	36.0	50.8	58.2	64.5	72.1
p_acetone/mm Hg	0	54.9	110.1	202.4	322.7	405.9	454.1	521.1
p_chloroform/mm Hg	632.8	548.1	469.4	359.7	257.7	193.6	161.2	120.7

100 ×x_acetone	0	11.8	23.4	36.0	50.8	58.2	64.5	72.1
p_acetone/mm Hg	0	54.9	110.1	202.4	322.7	405.9	454.1	521.1
p_chloroform/mm Hg	632.8	548.1	469.4	359.7	257.7	193.6	161.2	120.7
p_tota(mm Hg)	632.8	603.0	579.5	562.1	580.4	599.5	615.3	641.8