The correct option is B permanent hardness
Permanent hardness in water is due to the presence of chlorides and sulphates of calcium and magnesium.
Na2CO3 (washing soda) when added to hard water, precipitates out Ca+2 and Mg+2 ions as insoluble carbonates.
Na2CO3(aq) + CaCl2(aq) → CaCO3(ppt.)+ 2NaCl(aq)
These precipitates are then easily removed by filtration.