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Question

Water at 50C is filled in a cubical container of side 1 m. The thickness of the walls of the container is 1 mm. The container is surrounded by large amount of ice at 0C. The temperature of the water becomes 25C in 10 ln2 seconds. Choose the correct options.
[Given, specific heat of water =1 cal/(gmC); latent heat of fusion of ice =80 cal/gm; density of water =1gm/cm3; heat capacity of the container =1 J/K]

A
Thermal conductivity of the material is 70 J/mC
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B
Thermal conductivity of the material is 60 J/mC
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C
Mass of the ice melted is 312.5 kg
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D
Mass of the ice melted is 252 kg
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Solution

The correct options are
A Thermal conductivity of the material is 70 J/mC
C Mass of the ice melted is 312.5 kg
Let temperature of water at any instant be T, then heat current
i=kAx.(T0)(1)
where A=6a2=6 m2;x= thickness =1 mm=103 m
Rate of heat lost from water, dQdt=+msdTdt(2)
Ratw of heat lost from water = Rate of heat transfer through the wall
So, we get from (1)&(2),msdTdt=kATx2550dTT=kAmsx10n20dtln(2)=kAmsx10(ln2) So, kA(10)msx=1

On Putting values we get k=msx10A=(103kg)(4.2×103J/kgC)103m10×(6m3)=k=70J/mC
As we know, total heat transferred through the container = total heat absorbed by ice.
Q=dQ=kAxTdt Lost by water. Q=mSΔT=103×4200×25J=(10gm)(1 cal) (25)=miceL
mice=(106×2580)gm=2500080kg=312.5kg
mass of ice meited =312.5kg

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