The correct option is B expand
Water is cooled from 4∘C to 0∘C. It is called "Anomalous expansion of water", i.e. The expansion between 4 and 0 is due to the formation of larger clusters in the water molecules.
When water molecules go from 4∘C to 0∘C, they are forming groups in small lattices, what increases volume and decreases density. When water ices, then all their molecules are forming that lattice, as mineral crystals do, with the volume expanded.
Above 4∘C, thermal expansion sets as thermal vibrations of the OH bonds of water becomes more vigorous, tending to shove the molecules farther apart and water expands.
As a result of this water at 4∘C is denser than that at 0∘C. This causes floating of ice on water during winter. Bursting of pipes is also due to anomalous expansion.
Thus, Option B is correct.