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Question

Water rises to a height of 20 cm in a capillary tube and mercury falls to a depth of 3.5 cm in the same capillary tube. If the density of mercury is 13.6 g cm3 and its angle of contact is 135 and density of water is 1 g cm3 and its angle of contact is 0, then the ratio of surface tensions of the two liquids is approximately equal to

A
1 : 14
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B
5 : 17
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C
1 : 5
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D
5 : 27
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Solution

The correct option is B 5 : 17
The height h through which a liquid will rise in a capillary tube of radius r is given by
h=2 cos θrρg
whose S is the surface tension, ρ is the density of the liquid and θ is the angle of contact.
For identical capillary tubes, radius remains same. Hence we can say that
h1h2=2S1cos θ1rρ1g×rρ2g2S2cos θ2
h1h2=S1cos θ1ρ1×ρ2S2cos θ2
S1S2=h1h2×cos θ2cos θ1×ρ1ρ2 .......(1)
Given,
Rise in capillary tube containing water (h1)=20 cm
Fall in capillary tube containing mercury (h2)=3.5 cm
Density of water (ρ1)=1 g/cm3
Density of mercury (ρ2)=13.6 g/cm3
Angle of contact of water with capillary tube (θ1)=0
Angle of contact of mercury with capillary tube (θ2)=135
Thus from (1),
S1S2=203.5×cos 135cos 0×113.6
S1S2=0.29.
S1S25:17
Thus, option (b) is the correct answer.

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