The correct option is
B exists even when circuit is not used
The explanation for correct answer
Option B
- Emf is the electromotive force in the circuit.
- It is the voltage that remains if no current is flowing through the circuit.
- Therefore it exists when circuit is not used.
The explanation for incorrect answers
Option A
- Emf is independent of the resistance of the circuits.
Option C
- The potential difference is proportional to the circuit's resistance and hence differs from emf.
Option D
- Emf exists in cell or battery not across the circuit.
Hence, option (B) is the correct answer.