Each halogen combines with another halogen to form several compounds known as interhalogen compounds.
They can be prepared by direct combination, or by the action of a halogen on a lower interhalogen, the product formed depends on the conditions.
i) Cl2+F2(equal volume)473K⟶Δ2ClF
ii) IF2+F2(excess)573K⟶IF7(AX7type)
iii) Cl2+3F2(excess)573K⟶(AX3type)2ClF3
iv) Br2+5F2(excess)⟶(AX5type)2BrF5.