Radical, also calledFree Radical, inchemistry,moleculethat contains at least one unpaired electron. Most molecules contain even numbers of electrons, and the covalent chemical bonds holding the atoms together within a molecule normally consist of pairs of electrons jointly shared by the atoms linked by the bond. Most radicals may be considered to have arisen by cleavage of normal electron-pair bonds, every cleavage having produced two separate entities, each of which contains a single, unpaired electron from the broken bond (in addition to all the rest of the normal, paired electrons of the atoms).