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Question

What are the average distance and the most probable distance of an electron from the nucleus in the 1s orbital of a hydrogen atom? (a0=the radius of the first Bohr orbit)


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Solution

Most probable distance:

  • The most probable distance is the range of the orbit in which the electron is most likely to be.
  • vmps=2RTM
  • The most likely distances of an electron out from the nucleus in a hydrogen atom's 1s orbital is a0.
  • a0 has a value of 0.529A°.
  • As a result, the most probable distances of an electron from the nucleus in a hydrogen atom's 1s orbital is 0.529A°.

The average distance:

  • the average distance is the expected value of the length of an electron out from the nucleus.
  • vav=8RTπM
  • The average distance of an electron out from the nucleus in a hydrogen atom's 1s orbital is 1.5a0.
  • a0 has a value of 0.529A°.
  • As a result, the average distance of an electron from the nucleus in a hydrogen atom's 1s orbital is 0.794A°

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