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Question

What are the constituent amines formed when the mixture of (i) and (ii) undergoes Hoffmann bromamide degradation?

Ph(o−D)CONH2(i)PhCO15NH2(ii)

A
Ph(oD)NH2 Ph(oD)15NH2
PhNH2 Ph15NH2
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B
Ph(oD)NH2 Ph15NH2
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C
Ph(oD)15NH2 Ph15NH2
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D
Ph15NHD PhNH2
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Solution

The correct option is B Ph(oD)NH2 Ph15NH2
Solution:- (B)
Since the reaction is intramolecular, no cross product will be formed.
  • Ph(oD)CONH2Br2−−KOHpH(oD)NH2
  • PhCONH2PhNH2

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