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Crystal Field Split in Octahedral Complexes

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Question

What are the 'm' values for dxy, dyz, dzx & dx^2-y^2 orbitals if 'm' value of dz^2 orbital is 0 ?

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Solution

Dear Student,

Possible values which m can have depend upon l. m may have values which range from -l through 0 to +l.
For d-orbital, l=2
Therefore, m = -2,-1,0,+1,+2

If d_z² has m=0, then
d_xy, m=-2
d_yz, m=-1
d_zx, m=+1
d_x²_-y², m=+2

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