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Standard XII
Chemistry
Synthesis of Phenols-I
what are the ...
Question
what are the major and minor product formed, if I add CYCLOHEXAN-1,2-DIOL in a acidic solution? (a type of pinacol-pinacolone rearrangement
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Q.
The oxidative cleavage of 1,2-diol by a periodic acid or periodic salt to give corresponding carbonyls is known as Malaprade oxidation.
Vicinal diols can also be oxidized to form aldehydes and ketones by lead tetraacetate. This oxidative cleavage is analogous to malaprade oxidation and is known as Criegee oxidation.
When Halohydrin is treated with
A
g
2
O
or Silver salt, it gives pinacol-pinacolone type rearrangement called semi-pinacol rearrangement.
List-I contains reactions and List-II contains products that can be formed.
Which of the following options has the correct combination considering reaction in List-I and their product(s) in List-II?
Q.
The oxidation cleavage of 1,2-diol by a periodic acid or periodic salt to give corresponding carbonyls is known as Malaprade oxidation.
Vicinal diols can also be oxidized to form aldehydes and ketones by lead tetraacetate. This oxidation cleavage is analogous to malaprade oxidation and is known as Criegee oxidation.
When Halohydrin is treated with
A
g
2
O
or Silver salt, it gives pinacol-pinacolone type rearrangement called semi-pinacol rearrangement.
List-I contains reactions and List-II contains products that can be formed.
Which of the following options has the correct combination considering reaction in List-I and their product(s) in List-II?
Q.
The oxidative cleavage of 1,2-diol by a periodic acid or periodic salt to give corresponding carbonyls is known as Malaprade oxidation.
Vicinal diols can also be oxidized to form aldehydes and ketones by lead tetraacetate. This oxidative cleavage is analogous to malaprade oxidation and is known as Criegee oxidation.
When Halohydrin is treated with
A
g
2
O
or Silver salt, it gives pinacol-pinacolone type rearrangement called semi-pinacol rearrangement.
List-I contains reactions and List-II contains products that can be formed.
Which of the following options has the correct combination considering reaction in List-I and their product(s) in List-II?
Q.
Predict the pinacol-pinacolone rearrangement product of:
Q.
What is R.D.S.of pinacol-pinacolone rearrangement?
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Standard XII Chemistry
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