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Question

What are the oxidation numbers for ClO?

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Solution

You're dealing with the hypochlorite anion, ClO, so right from the start you know that the oxidation numbers of the atoms that make up the anion must be equal to −1, the overall charge of the ion
This means that you can write
ONchlorine+ONoxygen=1
Now, oxidation numbers are all about electronegativity. As you know, oxidation numbers are assigned with one concept in mind - that more electronegative atoms will take the bonding electrons from the bond it has with a less electronegative atom.
When oxygen is paired with a less electronegative atom, its oxidation state is always equal to −2.
In this case, oxygen is indeed more electronegative than chlorine, so you can say that
ONchlorine+(2)=1
This means that you have
ONchlorine=1+2=+1
The oxidation numbers for the atoms that make up the ion are
+1Cl2O

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