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Question

What are the oxidation numbers in the compound H2O2?

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Solution

You assign oxidation numbers to the elements in a compound by using the Rules for Oxidation Numbers.
The important rules for this problem are:
  1. The oxidation number of H is +1, but it is -1 in when combined with less electronegative elements.
  2. The oxidation number of O in compounds is usually -2, but it is -1 in peroxides.
  3. The sum of the oxidation numbers of all the atoms in a neutral compound is 0.
The oxidation number of H is +1 (Rule 1).
If you know that H2O2 is hydrogen peroxide, you can immediately assign oxygen the ON=1.
If you don't know that H2O2 is hydrogen peroxide, you can use Rule 3.
The oxidation number of H is +1. For two H atoms, the sum is +2.
Since H2O2 has no charge, the total oxidation number of the two O atoms must be -2.
The oxidation number of one oxygen atom must be -1.

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