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Question

What are the oxidation numbers in the compound KCl?

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Solution

The oxidation number of K is +1. The oxidation number of Cl is 1.
You assign oxidation numbers to the elements in a compound by using the Rules for Oxidation Numbers. The important rules for this problem are:
  1. The oxidation number of a monatomic ion equals the charge of the ion.
  2. The oxidation number of a Group 1 element in a compound is +1.
  3. The oxidation number of a Group 17 element in a binary compound is -1.
  4. The sum of the oxidation numbers of all the atoms in a neutral compound is 0.
In your case, KCl is an ionic compound. It consists of K+ ions and Cl ions.
The oxidation number of K is +1 (Rules 1 and 2).
The oxidation number of Cl is 1 (Rules 1 and 3).
Note that Rule 4 also applies: +1 + (-1) = 0. KCl is a neutral compound. It has no charge.

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