What are the products of following reaction?
$C H_{3} C H_{2} - O H + P C l_{5} \to$

C H_{3} C H_{2} - C l + P O C l + H C l

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C H_{3} C H_{2} - C l + P O C l_{3} + H C l

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C H_{3} C H_{2} - C l + P O C l_{2} + H C l

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None of these

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Solution

The correct option is B $C H_{3} C H_{2} - C l + P O C l_{3} + H C l$
When Alcohol reacts with phosphorous halides gives Alkyl halides and by-products phosphoryl chloride $(P O C l_{3})$ and HCl.
Alkyl halides are best prepared from alcohols by phosphorous halides or thionyl chloride.

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Similar questions

C H_{3} C H_{2} - I I

C H_{3} C H_{2} - B r I i

C H_{3} C H_{2} - C l I i i

C H_{3} C H_{2} - F I V

I : C H_{3} C H_{3} + C l^{*} \to C H_{3} C H_{2} C l + H^{*}

I I : C H_{3} C H_{3} + C l^{*} \to C H_{3} C H_{2}^{*} + H C l

I I I : C H_{3} C H_{2}^{*} + C l_{2} \to C H_{3} C H_{2} C l + C l^{*}

I V : 2 C l^{*} \to C l_{2}

Predict the product C obtained in the following reaction of

$C H_{3} C H_{2} - C \equiv C H + H C l \to B H I - - \to C$

C H_{3} C H_{2} - O | | C - C H_{3} N a N O_{2} \to H C l

C H_{3} C H_{2} - C l

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