The correct option is A n = 4; l = 0; m = 0; ms = +1/2
The electronic configuration of scandium (Z = 21) is 1s22s22p63s23p63d14s2.
The 19th electron of scandium enters 4s orbital. Hence, n=4.
For an electron in s orbital l=0;m=0.
Hence, the values of the quantum numbers of 19th electron of scandium are n=4;l=0;m=0;ms=+1/2.