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Question

What are Y and Z in the following reaction sequence ?
CH2=CHBrNaNH2−−−−YHg2+/H−−−−−H2O;333KZ

A
Y ethyne, Z acetic acid
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B
Y ethyne, Z ethanal
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C
Y ethylamine, Z ethanal
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D
Y ethane, Z ethanol
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Solution

The correct option is B Y ethyne, Z ethanal

CH2=CHBrNaNH2−−−−HCCHHg2+/H−−−−−H2O;333KCH3CHO

NaNH2Na++NH2

CH2=CHBr+NH2HCCH+NH3

then the acetylene undergo the further reaction as given in figure.

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