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Question

What characteristics do you except from an electron-deficient hydride with respect to its structure and chemical reactions?

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Solution

Electron deficient compounds of hydrogen do not have sufficient number of electrons to form normal covalent bonds. Examples include hydrides of group 13 such as BH3,AlH3 etc.
They exist in polymeric forms such as B2H6,Al2H6. Thus, they make up their deficiency.
These compounds are electron acceptors (Lewis acids). They form complexes with Lewis bases.
B2H6+2NMe32BH3NMe3
B2H6+2CO2BH3CO

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