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Question

What do you understand by standard temperature and pressure?

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Solution

Some textbooks define it differently than others, but the newest IUPAC standard temperature and pressure are:
TSTP=0oC=273.15 K
PSTP=1 bar.

Some older ( and potentially fairly recent ) textbooks might say:
TSTP=0oC=273.15 K
PSTP=1 atm

The difference between the two pressures are subtle but significant:
1 bar=1.00000×105 Pa
1 atm=1.01325×105 Pa

This leads to a difference about 0.3 L for the molar volume (¯V=Vn) of an ideal gas at STP when you calculate it using the Ideal Gas Law: 22.7 L for the former, and 22.4 L for the latter.

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