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Acidity of Carboxylic Acids

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Question

What happens when acetic acid is treated with ethanol in the presence of concentrated $H_{2} S O_{4}$ ? Give the equation of the reaction.

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Solution

On reaction between ethanol and acetic acid in presence of concentrated $H_{2} S O_{4}$ gives a sweet smelling ester like process is called esterification. It is a reversible reaction as given above.

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Q. (a) What happens when ethanol reacts with ethanoic acid in the presence of a little of concentrated sulphuric acid? Write equation of the reaction involved.
(b) What happens when ethanol is heated with concentrated sulphuric acid at 170°C? Write the equation of the reaction which takes place.

What happens when acetic acid reacts with ethanol in presence of conc. H₂SO₄?

Q. Write balanced equation for : Acetic acid is warmed with ethanol in the presence of conc.

H_{2} S O_{4}

.

Q. An aliphatic unsaturated hydrocarbon

(A)

when treated with

H g S O_{4} / H_{2} S O_{4}

yields a compound

(B)

having molecular formula

C_{3} H_{6} O

(B)

on oxidation with concentrated

H N O_{3}

gives two compounds

(C)

(D)

(C)

when treated with

P {C l}_{5}

(E)

(E)

when reacts with ethanol gives a sweet smelling liquid

(F)

(F)

is also formed when

(C)

reacts with ethanol in the presence of concentrated

H_{2} S O_{4}

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(i) Identify the compound

A, B, C, D, E

F

.
(ii) Give the chemical equation for the reaction of

(C)

with chlorine in the presence of red phosphorous and name the reaction.

Q. The reaction of ethanol with ethanoic acid in presence of concentrated

H_{2} S O_{4}

, produces _____.

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Acidity of Carboxylic Acids

Standard XII Chemistry

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