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Question

What happens when
i) White phosphorous is heated with concentrated NaOH solution in an inert atmosphere of CO2.
ii) XeF6 undergoes partial hydrolysis.

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Solution

A. 1.White phosphorous dissolves in boiling NaOH solution in a atmospheric CO2, to give

Phosphine, (PH3).

2.The equation is P4+3NaOH+3H2O>PH3+3NaH2PO2.

B. When xenon hexaflouride undergoes partial hydrolysis it giving

XeF6+H2OXeOF4+2HF


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