- The molecular formula is the expression of the number of atoms of each element in one molecule of a compound.
- The molecular formula definition is the formula showing the actual number of each atom in a molecule.
- When the molar mass value is known, the Molecular Formula is calculated by the empirical formula.
- n = molar mass/mass of the empirical formula
- The molecular formula is often the same as an empirical formula or an exact multiple of it.
Example
- A compound contains 86.88% of carbon and 13.12% of hydrogen, and the molecular weight is 345.
- What will be the empirical and molecular formula of the compound?
To get the empirical and molecular formula of the compound following these steps
Multiply percent composition with the molecular weight
Carbon : 345 x 0.8688 = 299.736
Hydrogen : 345 x 0.1312 = 45.264
Divide each value by the atomic weight
Carbon : 299.736 / 12.011 = 24.995
Hydrogen : 45.264 / 1.008 = 44.91
Round off the values to closest whole number so that on next step
Molecular formula is C25H45
Since 5 is the common factor, the empirical formula is C5H9