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Question

What is alpha black phosphorus?


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Solution

α-black phosphorus

  • Black phosphorus is an allotropic form of phosphorus.
  • Black phosphorus is of two types: α-black phosphorus and β-black phosphorus.

Properties

  • Alpha black phosphorus is formed when red phosphorus is heated in a closed tube at a temperature of 803K.
  • It does not get oxidized in the air.
  • Alpha Black phosphorus is more stable than beta one. Alpha consists of opaque monoclinic or rhombohedral crystals, while beta has corrugated sheets that form flaky layered crystals.

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