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Question

What is difference between physisorption and chemisorption ?

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Solution

S.NOPhysisorptionChemisorption1.It occurs due to van der waalsIt is formed by the forces.formation of chemical bonds.2.It is not specific in natureIt is highly specific in nature3.It is reversible in natureIt is irreversible4.Enthalpy of adsorption is lowEnthalpy of adsorption is(appr.2040 kJ mol1)high(appr.80240 kJ mol1)5.It depends on the nature ofIt also depends on the naturegas.More easily liqueliableof gas.Gases which can reactgases are adsorbed readilywith the adsorbent,showchemisorption.6.Low temperature is favourableHigh temperature is favourablefor physisorption.for chemisorption.7.No appreciable activationHigh activation energy isenergy is requiredsometimes required8.It results into multimolecularIt results into unimolecular layerlayers on the adsorbent surfaceunder high pressure.


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