Disproportionation is a specific type of redox reaction in which a species is simultaneously reduced and oxidised to form two different products.
In this reaction the chemical bond in the molecular ion is broken and one mercury atom is reduced to mercury(0) and the other is oxidized to mercury(II).
Chlorine gas reacts with dilute sodium hydroxide to form sodium chloride, sodium chlorate and water. The ionic equation for this reaction is as follows
3Cl2+6OH−→5Cl−+ClO−3+3H2O
The chlorine gas reactant is in oxidation state 0. In the products, the chlorine in the Cl− ion has an oxidation number of -1, having been reduced, whereas the oxidation number of the chlorine in the ClO−3 ion is +5, indicating that it has been oxidized.