Enthalpy is an extensive property. In general, if enthalpy of an overall reaction A → B along one route is ΔrH and ΔrH and ΔrH1, ΔrH2, ΔrH3 ⋯ represent enthalpies of intermediate reactions leading to product B. What will be the relation between ΔrH overall reaction and ΔrH1, ΔrH2 ⋯ etc for intermediate reactions.