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Question

What is formed as a predominant product in the following reaction?

A
CHI3
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B
CH2I
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C
CH3I
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D
None of the above
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Solution

The correct option is A CHI3
Iodoform test is used to check the presence of carbonyl compounds with the structure RCOCH3 or alcohols with the structure RCH(OH)CH3 in a given unknown substance.

When Iodine and sodium hydroxide are added to a compound that contains either a methyl ketone or a secondary alcohol with a methyl group in the alpha position, a pale yellow precipitate of iodoform or triiodomethane is formed. It can be used to identify aldehydes or ketones. If an aldehyde gives a positive iodoform test, then it must be acetaldehyde since it is the only aldehyde with a CH3C=O group.


Hence, the correct answer is option (a).

Steps Involved in Iodoform Reaction:

Step-1: Halogenation of methyl ketone:

Formation of iodoform​:

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