What is formed as a predominant product in the following reaction?
A
CHI3
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B
CH2I
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C
CH3I
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D
None of the above
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Solution
The correct option is ACHI3 Iodoform test is used to check the presence of carbonyl compounds with the structure R−CO−CH3 or alcohols with the structure R−CH(OH)−CH3 in a given unknown substance.
When Iodine and sodium hydroxide are added to a compound that contains either a methyl ketone or a secondary alcohol with a methyl group in the alpha position, a pale yellow precipitate of iodoform or triiodomethane is formed. It can be used to identify aldehydes or ketones. If an aldehyde gives a positive iodoform test, then it must be acetaldehyde since it is the only aldehyde with a CH3C=O group.