The chemical action that occurs in the cell while the current is flowing causes hydrogen bubbles to form on the surface of the anode. This action is called polarization. Some hydrogen bubbles rise to the surface of the electrolyte and escape into the air, some remain on the surface of the anode. If enough bubbles remain around the anode, the bubbles form a barrier that increases internal resistance. When the internal resistance of the cell increases, the output current is decreased and the voltage of the cell also decreases.
A cell that is heavily polarized has no useful output. There are several methods to prevent polarization or to depolarize the cell.