Radioactivity is the process by which a nucleus of a unstable atom loses energy by emitting radiation, including alpha particles, beta particles, gamma rays and conversion electrons.
Rate of decay of a nucleus is directly proportional to its quantity i.e. −dNdt∝N
Thus we get dNdt=−λN where λ=0.693T1/2 is proportionality constant
Integrating both sides, ∫NNodNN=∫to−λt where No is the amount of nucleus initially
⟹lnN∣∣∣NNo=−λt∣∣∣to
⟹lnNNo=−λt
⟹NNo=e−λt
⟹ Amount of nuclei left after time t, N=Noe−λt
Given : Half-life of a substance T1/2=5 days
As the substance gets disintegrated by 31/32th of its initial mass in time t.
Thus amount of substance left, N=(1−3132)No=132No
From above equation:
132No=Noe−λt
132=e−0.693T1/2t
ln132=−0.693T1/2t
−3.4657=−0.6935×t
⟹t=25 days