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Amines as Bases

What is the a...

Question

What is the action of sodium nitrite and hydrochloric acid on ethanamine, N-ethylethanamine and N, N-diethylethanamine?

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Solution

Diethylamine reacts with NaNO2 +dilHCl gives Nitroso compound

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Q. In the diazotisation of aniline with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to :

Q. In the diazotization of aryl amines with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to :

H - C O O H > P h - C O O H > C H_{3} - C O O H

(acidic nature)

C F_{3} - C O O H > C C I_{3} - C O O H > C H_{2} - C O O H

(Acidic nature)

N - m e t h y l m e t h a n a m i n e > m e t h a n a m i n e > N, N - d i m e t h y l m e t h a n a m i n e

(Basic nature in aqueous phase)

N, N - d i e t h l e t h a n a m i n e > N - e t h y l e t h a n a m i n e > E t h a n a m i n e

(Basic nature in aqueous phase)Then the correct order is:

Q. Fill in the blanks:
Benzene diazonium chloride is formed when _________ is treated with aqueous sodium nitrite and hydrochloric acid.

Q. Which of the following arylamines will not form a diazonium salt on reaction with sodium nitrite in hydrochloric acid?

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Amines as Bases

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