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Question

What is the basic principle behind the simple distillation process?

A
Sufficient difference in the boiling points of two miscible liquids and the two liquids should boil without decomposition.
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B
The two liquids should be immiscible.
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C
The two liquids should have a molecular weight greater than 200 g/mol.
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D
Difference in boiling and melting points of two miscible liquids should be less than 30C.
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Solution

The correct option is A Sufficient difference in the boiling points of two miscible liquids and the two liquids should boil without decomposition.
In a mixture of two or more miscible liquids, separation of various liquids depends on their boiling points. The liquid having a lower boiling point boils first and can be obtained first from the fractionating column than the liquid having a higher boiling point. In simple distillation, sufficient difference in the boiling points of two miscible liquids must be there and the two liquids should boil without decomposition.

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