The correct option is C XA=13
The expression for the rate of effusion is nA/tnB/t=√MBMA
The expression for the composition of mixture is n1M1+n2M2x1+x2=Mmix
Thus, X1M1+(1−X1)M2=Mmix
⇒X1=25,X2=35
The ratio ⇒XAXB=23√72128=12
Hence, XA=13,XB=23
Thus, the composition of the gas that diffused out initially from 2nd container is XA=13,XB=23.