What is the concentration of CO in equilibrium at 25oC in a sample of a gas originally containing 1.00molL−1 of CO2? For the dissociation of CO2 at 25oC. Kc=2.96×10−92
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Solution
CO2(g)⇋2CO(g)+O2(g) At equi.(1−2x)(2x)(x) Applying law of mass action Kc=[O2][CO]2[O2]2=2.96×10−92 It can be assumed that 1−2x=1.0 as Kc is very small. So, 4x3=2.96×10−92 or x=1.956×10−31molL−1 [CO]=2x=3.90×10−31molL−1