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Question

What is the coordination number of sodium in Na2O?

A
6
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B
4
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C
8
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D
2
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Solution

The correct option is A 4
Na2O has antifluorite crystal structure. In this structure negative ions form the Cubic Closest Packed arrangement so that each positive ion is surrounded by 4 negative ions and each negative ion is surrounded by 8 positive ions. So coordination no. of Na+ is 4.

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