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Question

What is the correct relationship between the pHs of isomolar solutions of sodium oxide (pH1), sodium sulphide (pH2), sodium selenide pH3) and sodium telluride pH4) ?

A
pH1>pH2pH3>pH4
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B
pH1<pH2<pH3<pH4
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C
pH1<pH2<pH3pH4
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D
pH1>pH2>pH3>pH4
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Solution

The correct option is D pH1>pH2>pH3>pH4
Acidic character increases in the order
H2O<H2S<H2Se<H2Te
Basic character of conjugate bases will be in the order
O2>S2>Se2>Te2
More the basic character, more the pH
pHs are in the order
pH1>pH2>pH3>pH4.

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