What is the correct sequence of reagents used for coverting nitrobenzene into m-dibromobenzene?
A
NaNO2⟶/HCl⟶/KBr⟶/H+⟶
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B
Sn/HCl⟶/Br2⟶/NaNO2⟶/NaBr⟶
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C
Br2/Fe⟶/Sn/HCl⟶/NaNO2/HCl⟶/CuBr/HBr⟶
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D
Sn/HCl⟶/KBr⟶/Br2⟶/H+⟶
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Solution
The correct option is CBr2/Fe⟶/Sn/HCl⟶/NaNO2/HCl⟶/CuBr/HBr⟶ First step is the bromination of nitrobenzene, NO2 is a meta directing group so meta-bromo product is formed. Second step is reduction of −NO2 to −NH2 group by Sn/HCl reagent. In third step, amine undergoes diazotisation reaction to give diazonium salt followed by reaction with CuBr to give the desired product.