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Question

What is the correct sequence of reagents used for coverting nitrobenzene into m-dibromobenzene?

A
NaNO2/HCl/KBr/H+
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B
Sn/HCl/Br2/NaNO2/NaBr
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C
Br2/Fe/Sn/HCl/NaNO2/HCl/CuBr/HBr
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D
Sn/HCl/KBr/Br2/H+
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Solution

The correct option is C Br2/Fe/Sn/HCl/NaNO2/HCl/CuBr/HBr
First step is the bromination of nitrobenzene, NO2 is a meta directing group so meta-bromo product is formed. Second step is reduction of NO2 to NH2 group by Sn/HCl reagent. In third step, amine undergoes diazotisation reaction to give diazonium salt followed by reaction with CuBr to give the desired product.

Hence, option (d) is correct.

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