Collision Theory: According to this theory, the reactant molecules are assumed to be hard spheres, and reaction is postulated to occur when molecules collide with each other.
Drawbacks of Collision Theory:
This theory is only applicable to simple gaseous molecules.
Collision theory does not explain energy activation barriers.
This theory considers atoms/ molecules to be hard spheres and ignores the structural aspect of atoms/molecules.
This theory is not applicable to reversible reactions.