Question

What is the EAN (effective atomic number) of the underlined atom in the following complex?

$\left[\underset{–}{Fe}\right(CN{)}_6{]}^{4-}$

Answer 1

The expression for the effective atomic number EAN is as given below.

$EAN=Z-X+Y$

Here, Z is the atomic number of metal,

X is the number of electrons lost during the formation of the metal ion from its atom and

Y is the number of electrons donated by the ligands.

For $\left[\underset{–}{Fe}\right(CN{)}_6{]}^{4-}$,

$Z=26,X=2$ and $Y=6\times 2=12e^{-}$.

Hence,

$EAN=26-2+12=36$.

Hence, the EAN of $\left[\underset{–}{Fe}\right(CN{)}_6{]}^{4-}$ is 36.