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Polymerisation of Alkenes

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What is the effect of steric hindrance on sn1 reaction?

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What is steric hindrance & steric effects?

Q. Assertion :Due to ortho effect basic nature of aniline decreases. Reason: It is due to steric hindrance because of solvation of cation.

Q. Statement- I:

(C H_{3})_{2} C H C H O

mainly undergoes Cannizzaro reaction when heated with the strong alkali.
Statement- II : Steric hindrance prevents aldol condensation.

Q. Arrange all the isomers of cresol in the increasing order of steric hindrance.

Q. Assertion (A) :

C H_{3} C H O

is more reactive than

C H_{3} C O C H_{3}

Reason (R) : The

> C = O

C H_{3} C H O

experiences more steric hindrance.

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