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Standard XII
Chemistry
Ostwald Dilution Law
What is the e...
Question
What is the effect on specific conductance and equivalent conductance on dilution ? (On dilution ions undergoes further ionization and yields more ions)
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Q.
Assertion :On increasing dilution, the specific conductance keep on increasing. Reason: On increasing dilution, degree of ionization of weak electrolyte increases and mobility of ions also increases.
Q.
Assertion :Specific conductance decreases with dilution whereas equivalent conductance increases. Reason: On dilution, number of ions per
c
c
decreases but total number of ions increases considerably.
Q.
What is the effect of dilution on specific, molar, equivalent conductance?
Q.
Assertion :Conductivity of weak electrolytic solution decreases with dilution whereas equivalent conductivity, molar conductivity increases with dilution. Reason: On dilution, the ionic mobility and number of ions present in solution increases but the number of ions per mL decreases.
Q.
Consider the following statements.
(i) Molar conductance of
H
+
is much higher than those of other ions
(ii) Equivalent conductivity and molar conductivity increase with dilution
(iii) Specific conductivity decreases with dilution
(iv) Conductance
K
+
<
N
a
+
<
L
i
+
in water
Identify the correct statement.
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