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Question

What is the empirical formula of a compound containing 36.5% sulfur and 63.5% iron?

A
FeS
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B
Fe63S36
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C
Fe2S
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D
Fe2S2
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E
2FeS
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Solution

The correct option is A FeS
100 g of the compound will contain 36.5gS and 63.5 g Fe.
The atomic masses of S and Fe are 32.1 g/mol and 55.8 g/mol respectively.
The number of moles are obtained by dividing mass with molar mass.
The number of moles of S =36.532.1=1.137 moles
The number of moles of Fe =63.555.8=1.137
Hence, the ratio of the number of moles of Fe to the number of moles of S is 1.137:1.137=1:1.
The empirical formula of the compound is FeS.

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