What is the equilibrium concentration of each of the substances in the equilibrium when the initial concentration of ICl was 0.78 M?
2ICl(g)↔l2(g)+Cl2(g); Kc=0.14
The given reaction is:
2ICl(g)↔I2(g)Cl2(g)Ionic cone.0.78 M00At equilibrium(0.78−2x) MxMxM
Now we can wirte, [I2][Cl2][ICl]2=Kc
⇒x×x(0.78−2x)2=0.14⇒x2(0.78−2x)2=0.14⇒x0.78−2x=0.374⇒x=0.292−0.748x⇒1.748x=0.292⇒x=0.167
Hence, at equilibrium
[H2]=[I2]=0.167 M[HI]=(0.78−2×0.167) M=0.446 M