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Question

What is the equilibrium constant expression, Kc for the reaction given below? Also, what is the equilibrium constant expression, Kp in terms of pressure.


BaSO4(s)BaO(s)+SO3(g)

A
Kc=[SO3], Kp=PSO3
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B
Kc=[SO3][BaO], Kp=PSO3
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C
Kc=[SO3][BaO][BaSO4], Kp=PSO3
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D
None of these
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Solution

The correct option is A Kc=[SO3], Kp=PSO3
For the given equilibrium reaction,

The equilibrium constant expression, Kc=[SO3]

and the equilibrium constant expression, Kp=PSO3

Note: The concentrations of solids do not appear in the equilibrium constant expression.

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