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Question

What is the final product in the given reaction?
CH3CH2ClKCN−−XNi/H2−−−Y

A
CH3CH2CH2NHCOCH3
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B
CH3CH2CH2NH2
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C
CH3CH2CH2CONHCH3
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D
CH3CH2CH2CONHCOCH3
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Solution

The correct option is B CH3CH2CH2NH2
Potassium cyanide reacts with ethyl chloride to give ethyl cyanide because KCN is predominantly ionic. Hence CN exists as free ions in solution​. C site is more nucleophilic than N site and available to attack the ethyl chloride​. Hence, the major product will be ethyl cyanide​.

Ni/H2 helps in reduction of CN to CH2NH2
CH3CH2ClKCN−−CH3CH2CN(X)Ni/H2−−−CH3CH2CH2NH2(Y)

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