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Question

What is the formula of the coordination complexes when a Ni2+ ion is bound to two water molecules and two bidentate oxalate ions ?

A
[Ni(H2O)2(C2O4)2]2
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B
[Ni(H2O)3(C2O4)2]2
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C
[Ni(H2O)2(C2O4)2]2+
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D
[Ni(H2O)2(C2O4)4]2
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Solution

The correct option is A [Ni(H2O)2(C2O4)2]2
When Ni2+ ion is bound to two water molecules and two bidentate oxalate ions then the formula of the co-ordination complex is-

[Ni(H2O)2(C2O4)2]2.
Here 2 water molecules bound to Ni atom and 2 ambident ligands are also bound, the overall charge is -2

Hence, option A is correct.

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