What is the hybridization of central atom in following? $P H_{3}, P H_{4}^{+},$

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Solution

(i) $P H_{3} ⟶ \frac{V a l e n c e e^{-} o f c e n t r a l a t o m + N u m b e r o f u n i v a l e n t a t o m + \pm c h a r g e}{2}$
$\Rightarrow \frac{5 + 3}{2} = 4$
$∴ s p^{3}$
(Refer to Image 1)

(ii) $P H_{4}^{+} ⟶ \frac{5 + 4 - 1}{2} = 4 = s p^{3}$
(Refer to Image 2)

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